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Rauchfuss Group

Journal Articles (2004-2008)


2008

"Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases", B. E. Barton, M. T. Olsen, T. B. Rauchfuss, J. Am. Chem. Soc., 2008, 130, 16834-16835.

"[Fe Fe]-Hydrogenase Models and Hydrogen: Oxidative Addition of Dihydrogen and Silanes", Z. M. Heiden, G. Zampella, L. De Gioia, T. B. Rauchfuss, Angew. Chem. Int. Ed., 2008, 47, 9756-9759.

"Nitrosyl Derivatives of Diiron Dithiolates Related to FeFe Hydrogenase", M. T. Olsen, A. K. Justice, F. G. Gloaguen, T. B. Rauchfuss, S. R. Wilson, Inorg. Chem. 2008, 47, 11816-11824.

"Precursors to [FeFe]-Hydrogenase Models: Syntheses of Fe2(SR)2(CO)6 from CO-Free Iron Sources", P. I. Volkers, C. A. Boyke, J. Chen, T. B. Rauchfuss, C. M. Whaley, S. R. Wilson, H. Yao, Inorg. Chem. 2008, 47, 7001-7008.

"X-ray Photochemistry in Iron Complexes from Fe(0) to Fe(IV) – Can a Bug Become a Feature?" S. J. George, J. Fu, Y. Guo, O. B. Drury, S. Friedrich, T. B. Rauchfuss, P. I. Volkers, J. C. Peters, V. Scott, S. D. Brown, C. M. Thomas, S. P. Cramer, Inorg. Chim. Acta, 2008, 361, 1157-1165.

"Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the FeFe-Hydrogenase Active Site", M. T. Olsen, M. Bruschi, L. De Gioia, T. B. Rauchfuss, S. R. Wilson, J. Am Chem. Soc. 2008, 130, 12021-12030.

"Redox and Structural Properties of Models for the H ox State of the [FeFe]-Hydrogenase: Progress and Challenges", A. K. Justice, L. De Gioia, M. J. Nilges, T. B. Rauchfuss, S. R. Wilson, G. Zampella, Inorg. Chem., 2008, 47, 7405-7414.

"Terminal Hydride in [FeFe]-Hydrogenase Model Has Lower Potential for H2 Production than the Isomeric Bridging Hydride", B. E. Barton, T. B. Rauchfuss, Inorg. Chem., 2008, 47, 2261-2263.

"Supramolecular Architectures Based on Organometallic Half-sandwich Complexes", T. B. Rauchfuss, K. Severin, in "Molecular Nanostructures" J. Atwood, J. Steed, eds. Wiley-VCH, 2008; 179-201.

"Desulfurization of Petroleum Streams Utilizing Multi-Ring Aromatic Alkali Metal Complex", M. Siskin, R. D. Myers, R. Beardon, T. B. Rauchfuss, U. S. Patent filed November, 2007, assigned to ExxonMobil.

"Expanded Cyanometallate Cages Derived from Dimetallic Dicyanide Building Blocks: {[Cp*Rh]4[Fe2(S2C3H6)(CN)2(CO)4]6}4- ", J. L. Boyer, T. B. Rauchfuss, S. R. Wilson, Comptes Rendus, 2008, 11, 922-925.

"Lewis Base Adducts Derived from Transfer Hydrogenation Catalysts: Scope and Selectivity," Z. M. Heiden, B. J. Gorecki, T. B. Rauchfuss, Organometallics 2008, 28, 1542-1549.

"Diiron Dithiolato Carbonyls Related to HoxCO State of [FeFe]-Hydrogenase," A. K. Justice, M. A. Nilges, T. B. Rauchfuss, S. R. Wilson, L. De Gioia, G. Zampella, J. Am Chem.Soc. 2008, 130, 5293-5301.

"Characterization of the Fe Site in Methanothermobacter marburgensis Hydrogenase (mHmd) via Nuclear Resonant Vibrational Spectroscopy (NRVS)," Y. Guo, H. Wang, Y. Xiao, S. Vogt, R. K. Thauer, S. Shima, T. B. Rauchfuss, P. I. Volkers, E. Alp, W. Sturhahn, Y. Yoda, S. P. Cramer, Inorg. Chem., 2008, 47, 3969-3977.

"Coordination Chemistry of a Model for the GP Cofactor in the Hmd Hydrogenase: Hydrogen-Bonding and Hydrogen-Transfer Catalysis," A. M. Royer, T. B. Rauchfuss, S. R. Wilson, Inorg. Chem., 2008, 46, 395-397.

"Desymmetrized Diiron Azadithiolates: A Step Toward Modeling the Fe-only Hydrogenases" J. L. Stanley, Z. M. Heiden, T. B. Rauchfuss, S. R. Wilson, L. De Gioia, G. Zampella, Organometallics 2008, 27, 119-125.

"Redox-Switched Oxidation of Dihydrogen using a Non-innocent Ligand," M. R. Ringenberg,S. L. Kokatam, Z. M. Heiden, T. B. Rauchfuss, J. Am. Chem. Soc, 2008, 130, 788-789.

2007

"Highlight: Models for the Hydrogenases Put the Focus Where It Should Be - Hydrogen" C. Mealli, T. B. Rauchfuss, Angew. Chem. Int. Ed.,2007, 46, 8942-8944.

"Extending the FeFe-Hydrogenase Motif: Protonation of Fe2(NR2)2L6", P. I. Volkers, T. B. Rauchfuss, J. Inorg. Biochem. (Stiefel Memorial Issue) 2007, 101, 1748-1751.

"Homogeneous Catalytic Reduction of Dioxygen Using Transfer Hydrogenation Catalysts", Z. M. Heiden and T. B. Rauchfuss, J. Am. Chem. Soc., 2007, 129, 14303-14310.

"Unsaturated Mixed Valence Diiron Dithiolate Model for the Hox State of the [FeFe]-Hydrogenase", A. K. Justice, T. B. Rauchfuss, S. R.Wilson, Angew. Chem. Int. Ed., 2007, 46, 6152-6154.

"A Promising Mimic of Hydrogenase Activity", T. B. Rauchfuss, Science 2007, 316, 553-4.

"Cyanometallate Cages with Exchangeable Terminal Ligands", J. L. Boyer, H. Yao, M. L. Kuhlman, T. B. Rauchfuss, S. R. Wilson, Eur. J. Inorg. Chem. (invited paper for 10th anniversary issue) 2007, 2721-2728.

"Tri-substituted Diiron Dithiolates Containing Chelating Diphosphines - Electronic and Structural Models for Fe-only Hydrogenases", A. K. Justice, G. Zampella, L. De Gioia, J. I. van der Vlugt, T. B. Rauchfuss, Inorganic Chemistry 2007, 46, 00000

"Lewis vs. BrØnsted-Basicities of Diiron Dithiolates: Spectroscopic Detection of the 'Rotated Structure' and Remarkable Effects of Ethane- vs. Propanedithiolate", A. K. Justice, G. Zampella, L. De Gioia, T. B. Rauchfuss, Chemical Communications, 2007, 2019-2021.

"Studies on the Condensation Pathway to and Properties of Diiron Azadithiolate Carbonyls", J. L. Stanley, T. B. Rauchfuss, S. R.Wilson, Organometallics, 2007, 26, 1907-1911.

"Evolution of Organo-cyanometallate Cages: Supramolecular Architectures and New Cs+-specific Receptors", J.L. Boyer, M.L. Kuhlman and T.B. Rauchfuss, Accounts of Chemical Research, 2007, 40, 233-242.

"Chelate Control of Diiron(I) Dithiolates Relevant to the Fe-only Hydrogenase Active Site", A. K. Justice, G. Zampella, L. De Gioia, J. I. van der Vlugt, T. B. Rauchfuss, Inorg. Chem. 2007, 46, 1655-1664.

"Redox-Switched Complexation/Decomplexation of K+ and Cs+ by Molecular Cyanometalate Boxes", J. L. Boyer, M. Ramesh, H. Yao, T. B. Rauchfuss, S. R. Wilson, J. Am. Chem. Soc. 2007, 129, 1931-1936.

2006

"Proton-induced Lewis Acidity of Unsaturated Iridium Amides", Z. M. Heiden and T. B. Rauchfuss, J. Am. Chem. Soc. 2006, 128, 13048-13049.

"The Coordination Chemistry of the Propane-1,3-Dithiol-2-Carboxylic Acid (Asparagusic Acid) with Iron and Nickel", P. I. Volkers, Rauchfuss, T. B. S. R. Wilson, Eur. J. Inorg. Chem., 2006, 4793-99.

"Diruthenium Dithiolato Cyanides: Basic Reactivity Studies and a Post hoc Examination of Nature's Choice of Fe versus Ru for Hydrogenogenesis", A. K. Justice, R. C. Linck and T. B. Rauchfuss, Inorganic Chemistry 2006, 45, 2406-2412.

"Electron-Rich Diferrous Phosphine Thiolates Relevant to Fe-only Hydrogenase: Is Cyanide Nature’s Trimethylphosphane?" J. I. van der Vlugt, T. B. Rauchfuss, S. R. Wilson, Chem. Eur. J. 2006, 12, 90-98.

"MoS2(Me2PC2H4PMe2)2 (M= Mo, W): Acid-base Properties, Proton Transfer, and Reversible Protonolysis of Sulfido Ligands", S. J. Smith, C. M. Whaley, T. B. Rauchfuss and S. R. Wilson, Inorganic Chemistry 2006, 45, 679-687.

2005

"Electron-rich Diferrous-phosphane-thiolates Relevant to Fe-only Hydrogenase: Is Cyanide "Nature's Trimethylphosphane"?" J. I. van der Vlugt, T. B. Rauchfuss and S. R. Wilson, Chemistry-A European Journal 2005, 12, 90-98.

"Characterization Of a Diferrous Terminal Hydride Mechanistically Relevant to The Fe-Only Hydrogenases", J. I. van der Vlugt, T. B. Rauchfuss, C. M. Whaley and S. R. Wilson, Journal of the American Chemical Society 2005, 127, 16012-16013.

"Synthetic Models for Bioorganometallic Reaction Centers" Linck, R. C.; Rauchfuss, T. B.;, Chapter 5 in Bioorganometallic Chemistry, G. Jaouen, Ed. VCH, Weinheim,2005 403-435.

"Bis [(1,4,7,10,13,16-hexaoxacyclooctadecane)potassium] Carbonyltricyanorhodate(I) Acetonitrile Solvate", C. M. Whaley, T. B. Rauchfuss and S. R. Wilson, Acta Crystallographica, Section e (Structure Reports Online) 2005, 61, m1918-m1919.

"Organo-tricyanoborates as Tectons: Illustrative Coordination Polymers Based On Copper(I) Derivatives", H. J. Yao, M. L. Kuhlman, T. B. Rauchfuss and S. R. Wilson, Inorganic Chemistry 2005, 44, 6256-6264.

"Diferrous Cyanides as Models for the Fe-only Hydrogenases", C. A. Boyke, J. I. van der Vlugt, T. B. Rauchfuss, S. R. Wilson, G. Zampella and L. De Gioia, Journal of the American Chemical Society 2005, 127, 11010-11018.

"Syntheses and Crystal Structures of New Sulfido-bridged Ruthenium Clusters", M. Wunder, A. L. Eckermann, T. B. Rauchfuss and D. Fenske, Zeitschrift fur Anorganische und Allgemeine Chemie 2005, 631, 131-134.

"[Me8Pt4ReS4]- and Related Alkyl-Containing Clusters Derived from Tetrathiorhenate" Yao, H.; Rauchfuss, T. B.; Wilson, S. R. J. Organometal. Chem. 2005, 690, 193-196.

2004

"Dihydrogen Activation by a Diruthenium Analogue of the Fe-only Hydrogenase Active Site" Justice, A. K.; Linck, R. C.; Rauchfuss, T. B.; Wilson, S. R. J. Am. Chem. Soc. 2004, 126, 13214-13215.

"Competing H-H, S-S, and M-M Bond Formation in [Ru4S3(arene)4]z Clusters" Kuhlman, M. L.; Rauchfuss. T. B. Angew. Chem. Int. Ed. 2004, 43, 6742-6745.

"Condensation of [Ru3S2(cymene)3]2+ with Sulfide to Give the Dendridic Cluster [Ru9S8(cymene)6]2+" Kuhlman, M. L.; Rauchfuss, T. B. Organometallics 2004, 23, 5085-5087.

"Structural and Mechanistic Studies on Ion Insertion into the Molecular Box [CpCo(CN)3]4[Cp*Ru]4" Ramesh, M.; Rauchfuss, T. B. J. Organometal. Chem. 2004, 689, 1425-30.

"[Fe2(SR)2(µ-CO)(CNMe)6]2+ and Analogues: a New Class of Diiron Dithiolates as Structural Models for the Hoxair State of the Fe-only Hydrogenases" Boyke, C. A.: Rauchfuss, T. B.; Wilson, S. R.; Bénard, M.; Rohmer, M.-M., J. Am. Chem. Soc. 2004, 126, 15151-15160.

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"Synthesis and Characterization of the Hexagonal Prismatic Cage {THFpart of set[PhB(CN)3]6[Cp*Rh]6}6+" Kuhlman, M. L.; Yao, H.; Rauchfuss, T. B. Chem. Commun. 2004, 1370-1.

"Hybrid Cluster-Cages Formed via Cyanometallate Condensation: Cspart of setCo4Ru6S2(CN)12, Co4Ru9S6(CN)9, and Rh4Ru9S6(CN)9 Frameworks" Kuhlman, M. L.; Rauchfuss, T. B. Inorg. Chem. 2004, 43, 430-435.

"Electrosynthesis of ReS4. XAS Analysis of ReS2, Re2S7, and ReS4" Schwarz, D. E.: Frenkel, A. I.; Nuzzo, R. G.; Rauchfuss, T. B.; Vairavamurthy, A. Chem. Mater. 2004, 16, 151-158.

"Tricyanometallate Building Blocks and Organometallic Cyanide Cages" Contakes, S. M.; Klausmeyer, K. K.; Rauchfuss, T. B. Inorg. Synth. 2004, 34, 166-171.

"Research on Soluble Metal Sulfides: From Polysulfido Complexes to Functional Models for the Hydrogenases" Rauchfuss, T. B., Inorg. Chem. 2004, 43, 14-26.